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Author(s):   Sidhu, S.S.; Kiefer, J.H.; Lifshitz, A.; Tamburu, C.; Walker, J.A.; Tsang, W.
Title:   Rate of the retro-diels-alder dissociation of 1,2,3,6-tetrahydropyridine over a wide temperature range
Journal:   Int. J. Chem. Kinet.
Volume:   23
Page(s):   215 - 227
Year:   1991
Reference type:   Journal article
Squib:   1991SID/KIE215-227

Reaction:   1,2,3,6-Tetrahydropyridine1,3-Butadiene + CH2=NH
Reaction order:   1
Temperature:   850 - 1000 K
Pressure:  0.11 - 0.16 bar
Rate expression:   1.0x1014 [s-1] e-220334 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
850 2.89E0
875 7.03E0
900 1.63E1
925 3.61E1
950 7.68E1
975 1.57E2
1000 3.10E2