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Title: Rate of the retro-diels-alder dissociation of 1,2,3,6-tetrahydropyridine over a wide temperature range
Journal: Int. J. Chem. Kinet.
Volume: 23
Page(s): 215 - 227
Year: 1991
Reference type: Journal article
Squib: 1991SID/KIE215-227
Reaction:
1,2,3,6-Tetrahydropyridine → 1,3-Butadiene + CH2=NH
Reaction order:
1
Reference reaction:
3,4-Dihydro-2H-pyran → C2H4 + CH2=CHCHO
Temperature:
650 - 750
K
Pressure: 1.52 bar
Rate expression:
2.57x1014 [s-1] e-219502 [J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 650 | 5.90E-4 |
| 675 | 2.66E-3 |
| 700 | 1.07E-2 |
| 725 | 3.94E-2 |
| 750 | 1.33E-1 |