Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Tsang, W.
Title:   Chemical kinetic data base for combustion chemistry. Part V. Propene
Journal:   J. Phys. Chem. Ref. Data
Volume:   20
Page(s):   221 - 273
Year:   1991
Reference type:   Journal article
Squib:   1991TSA221-273

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1991TSA221-273   CH2O + ·CH2CH=CH2CH3CH=CH2 + HCO  300 - 2500   1.05E-11   1.90   7.61E04      2
  1991TSA221-273   CH3OH + ·CH2CH=CH2CH3CH=CH2 + (·)CH2OH  300 - 2500   4.33E-14   2.90   8.56E04      2
  1991TSA221-273   CH4 + ·CH2CH=CH2CH3CH=CH2 + ·CH3  300 - 2500   1.71E-14   3.40   9.73E04      2
  1991TSA221-273   C2H6 + ·CH2CH=CH2CH3CH=CH2 + ·C2H5  300 - 2500   5.71E-14   3.30   8.31E04      2
  1991TSA221-273   C2H4 + CH3CH=CH21-C5H10  300 - 2500   1.47E-15   2.20   1.43E05      2
  1991TSA221-273   C2H4 + CH3CH=CH2·CH2CH=CH2 + ·C2H5  300 - 2500   9.60E-11       2.16E05      2
  1991TSA221-273   C2H4 + CH3CH=CH2iso-C3H7 + C2H3  300 - 2500   2.96E-10   -0.65   3.08E05      2
  1991TSA221-273   C2H4 + CH3CH=CH2n-C3H7 + C2H3  300 - 2500   1.00E-10       3.16E05      2
  1991TSA221-273   C2H4 + ·CH2CH=CH2Cyclopentene +   300 - 2500   1.00E-14       4.81E04      2
  1991TSA221-273   C2H2 + CH3CH=CH2·CH2CH=CH2 + C2H3  300 - 2500   6.71E-11       1.96E05      2
  1991TSA221-273   C2H2 + ·CH2CH=CH2Cyclopentadiene +   300 - 2500   6.59E-10       1.04E05      2
  1991TSA221-273   C2H2 + ·CH2CH=CH2CH2=CHCH2CH=CH·  300 - 2500   5.30E-14       2.91E04      2
  1991TSA221-273   C3H8 + ·CH2CH=CH2CH3CH=CH2 + iso-C3H7  300 - 2500   1.91E-14   3.30   7.60E04      2
  1991TSA221-273   C3H8 + ·CH2CH=CH2CH3CH=CH2 + n-C3H7  300 - 2500   5.71E-14   3.30   8.31E04      2
  1991TSA221-273   iso-C4H10 + ·CH2CH=CH2CH3CH=CH2 + tert-C4H9  300 - 2500   1.02E-14   3.30   7.18E04      2
  1991TSA221-273   CH3CH=CH2·CH2CH=CH2 +   300 - 2500   2.50E15       3.63E05      1
  1991TSA221-273   iso-C4H10 + ·CH2CH=CH2CH3CH=CH2 + iso-C4H9  300 - 2500   8.63E-14   3.30   8.31E04      2
  1991TSA221-273   CH3CH=CH2·CH3 + C2H3  300 - 2500   1.18E18   -1.20   4.09E05      1
  1991TSA221-273   CH3CH=CH2 + CH3CH=CH21-C6H12  300 - 2500   3.22E-16   2.50   1.54E05      2
  1991TSA221-273   CH3CH=CH2 + CH3CH=CH2(CH3)2CHCH2CH=CH2  300 - 2500   4.40E-16   2.10   1.50E05      2
  1991TSA221-273   CH3CH=CH2 + CH3CH=CH2·CH2CH=CH2 + iso-C3H7  300 - 2500   8.10E-11       2.19E05      2
  1991TSA221-273   CH3CH=CH2 + CH3CH=CH2·CH2CH=CH2 + n-C3H7  300 - 2500   4.20E-10       2.31E05      2
  1991TSA221-273   CH3CH=CH2 + tert-C4H9iso-C4H10 + ·CH2CH=CH2  300 - 2500   6.64E-17   4.90   3.33E04      2
  1991TSA221-273   CH3CH=CH2 + tert-C4H9 → (CH3)3CCH2CH(·)CH3  300 - 2500   5.10E-15       2.46E04      2
  1991TSA221-273   CH3CH=CH2 + ·CH2CH=CH21-Methylcyclopentene +   300 - 2500   1.00E-14       4.81E04      2
  1991TSA221-273   CH3CH=CH2 + iso-C3H7C3H8 + ·CH2CH=CH2  300 - 2500   8.67E-16   4.00   3.38E04      2
  1991TSA221-273   CH3CH=CH2 + ·C2HC2H2 + ·CH2CH=CH2  300 - 2500   5.99E-12              2
  1991TSA221-273   CH3CH=CH2 + ·C2HC2H2 + CH3CH=CH  300 - 2500   2.01E-12              2
  1991TSA221-273   CH3CH=CH2 + ·C2HC2H2 + CH2=C(·)CH3  300 - 2500   2.01E-12              2
  1991TSA221-273   CH3CH=CH2 + ·C2HCH3CCH + C2H3  300 - 2500   2.01E-11              2
  1991TSA221-273   CH3CH=CH2 + ·C2HC2H5CCH + ·CH  300 - 2500   2.01E-11              2
  1991TSA221-273   CH3CH=CH2 + CH3O2·Methyloxirane + CH3  300 - 2500   6.59E-13       4.91E04      2
  1991TSA221-273   CH3CH=CH2 + CH3O2··CH2CH=CH2 + CH3OOH  300 - 2500   3.30E-12       7.13E04      2
  1991TSA221-273   CH3CH=CH2 + n-C3H7C3H8 + ·CH2CH=CH2  300 - 2500   1.69E-15   3.50   2.78E04      2
  1991TSA221-273   CH3CH=CH2 + CH3CH3OH + ·CH2CH=CH2  300 - 2500   2.97E-15   2.95   5.01E04      2
  1991TSA221-273   CH3CH=CH2 + ·CH3CH4 + ·CH2CH=CH2  300 - 2500   1.68E-15   3.50   2.38E04      2
  1991TSA221-273   CH3CH=CH2 + ·CH3sec-C4H9  300 - 2500   2.81E-13       3.10E04      2
  1991TSA221-273   CH3CH=CH2 + ·CH3iso-C4H9  300 - 2500   1.60E-13       3.35E04      2
  1991TSA221-273   CH3CH=CH2 + (·)CH2OHCH3OH + ·CH2CH=CH2  300 - 2500   1.99E-15   2.95   5.01E04      2
  1991TSA221-273   CH3CH=CH2 + HCOCH2O + ·CH2CH=CH2  300 - 2500   9.05E-13   1.90   7.12E04      2
  1991TSA221-273   CH3CH=CH2 + C2H3C2H4 + ·CH2CH=CH2  300 - 2500   1.68E-15   3.50   1.96E04      2
  1991TSA221-273   CH3CH=CH2 + C2H31,3-Butadiene + ·CH3  300 - 2500   1.20E-12       2.10E04      2
  1991TSA221-273   CH3CH=CH2 + C2H3CH2=CHCH=CHCH3 +   300 - 2500   1.20E-12       2.69E04      2
  1991TSA221-273   CH3CH=CH2 + CH3COCH3CHO + ·CH2CH=CH2  300 - 2500   7.82E-13   2.00   6.79E04      2
  1991TSA221-273   CH3CH=CH2 + HO2Methyloxirane + ·OH  300 - 2500   1.74E-12       5.94E04      2
  1991TSA221-273   CH3CH=CH2 + HO2·CH2CH=CH2 + H2O2  300 - 2500   4.33E-14   2.60   5.82E04      2
  1991TSA221-273   CH3CH=CH2 + ·OH·CH2CH=CH2 + H2O  300 - 2500   4.60E-13   2.00   -1247      2
  1991TSA221-273   CH3CH=CH2 + ·OH → CH3CH=CH + H2O  300 - 2500   3.16E-13   2.00   1.16E04      2
  1991TSA221-273   CH3CH=CH2 + ·OHH2O + CH2=C(·)CH3  300 - 2500   1.63E-13   2.00   6070      2
  1991TSA221-273   CH3CH=CH2 + iso-C4H9iso-C4H10 + ·CH2CH=CH2  300 - 2500   1.69E-15   3.50   2.78E04      2
  1991TSA221-273   CH3CH=CH2 + O2·CH2CH=CH2 + HO2  300 - 2500   1.00E-10       2.00E05      2
  1991TSA221-273   CH3CH=CH2 + H2 + ·CH2CH=CH2  300 - 2500   4.40E-13   2.50   1.04E04      2
  1991TSA221-273   CH3CH=CH2 + iso-C3H7  300 - 2500   2.19E-11       6527      2
  1991TSA221-273   CH3CH=CH2 + n-C3H7  300 - 2500   2.19E-11       1.36E04      2
  1991TSA221-273   CH3CH=CH2 + ·C2H5 → Products  300 - 2500   1.69E-13       3.01E04      2
  1991TSA221-273   CH3CH=CH2 + ·C2H5C2H6 + ·CH2CH=CH2  300 - 2500   1.69E-15   3.50   2.78E04      2
  1991TSA221-273   CH3CH=CH2 + → Products  300 - 2500   1.25E-12   2.15   -3326      2
  1991TSA221-273   CH3CH=CH2 + ·CH2CH=CH2 + ·OH  300 - 2500   1.56E-11   0.70   2.46E04      2
  1991TSA221-273   CH3CH=CH2 + ·OH + CH2=C(·)CH3  300 - 2500   5.40E-12   0.70   3.19E04      2
  1991TSA221-273   CH3CH=CH2 + ·OH + CH3CH=CH  300 - 2500   1.08E-11   0.70   3.75E04      2
  1991TSA221-273   CH3CH=CH2 + ·CH2CH3CH=CHCH3  300 - 2500   2.71E-12       2.21E04      2
  1991TSA221-273   H2 + ·CH2CH=CH2CH3CH=CH2 +   300 - 2500   1.39E-13   2.38   7.95E04      2
  1991TSA221-273   CH3CH=CH2 + ·CH2·CH2CH=CH2 + ·CH3  300 - 2500   1.20E-12       2.59E04      2
  1991TSA221-273   tert-C4H9 + ·CH2CH=CH2iso-C4H10 + CH2=C=CH2  300 - 2500   6.69E-13   -0.75   -549      2
  1991TSA221-273   tert-C4H9 + ·CH2CH=CH2CH3CH=CH2 + iso-C4H8  300 - 2500   1.00E-11   -0.75   -549      2
  1991TSA221-273   tert-C4H9 + ·CH2CH=CH2(CH3)3CCH2CH=CH2  300 - 2500   1.68E-11   -0.75   -549      2
  1991TSA221-273   ·CH2CH=CH2CH2=C=CH2 +   300 - 2500   1.40E13       2.51E05      1
  1991TSA221-273   ·CH2CH=CH2 + ·CH2CH=CH2CH3CH=CH2 + CH2=C=CH2  300 - 2500   1.40E-13       -1098      2
  1991TSA221-273   ·CH2CH=CH2 + ·CH2CH=CH2CH2=CHCH2CH2CH=CH2  300 - 2500   1.69E-11       -1098      2
  1991TSA221-273   ·CH2CH=CH2 + iso-C3H7C3H8 + CH2=C=CH2  300 - 2500   1.04E-12   -0.35   -549      2
  1991TSA221-273   ·CH2CH=CH2 + iso-C3H7CH3CH=CH2 + CH3CH=CH2  300 - 2500   5.18E-12   -0.35   -549      2
  1991TSA221-273   ·CH2CH=CH2 + ·C2H → Products  300 - 2500   8.00E-11              2
  1991TSA221-273   ·CH2CH=CH2 + iso-C3H7(CH3)2CHCH2CH=CH2  300 - 2500   2.59E-11   -0.35   -549      2
  1991TSA221-273   ·CH2CH=CH2 + CH3O2·CH2=CHCHO + CH3 +   300 - 2500   1.60E-11              2
  1991TSA221-273   ·CH2CH=CH2 + n-C3H7C3H8 + CH2=C=CH2  300 - 2500   1.20E-12       -549      2
  1991TSA221-273   ·CH2CH=CH2 + n-C3H7CH3CH=CH2 + CH3CH=CH2  300 - 2500   2.41E-12       -549      2
  1991TSA221-273   ·CH2CH=CH2 + n-C3H71-C6H12  300 - 2500   3.40E-11       -549      2
  1991TSA221-273   ·CH2CH=CH2 + CH3CH2O + CH3CH=CH2  300 - 2500   5.00E-11              2
  1991TSA221-273   ·CH2CH=CH2 + ·CH3CH4 + CH2=C=CH2  300 - 2500   8.07E-13   -0.32   -549      2
  1991TSA221-273   ·CH2CH=CH2 + ·CH31-C4H8  300 - 2500   2.72E-11   -0.32   -549      2
  1991TSA221-273   ·CH2CH=CH2 + HCOCH3CH=CH2 + CO  300 - 2500   1.00E-10              2
  1991TSA221-273   ·CH2CH=CH2 + (·)CH2OHCH2O + CH3CH=CH2  300 - 2500   3.01E-11              2
  1991TSA221-273   ·CH2CH=CH2 + HCOCH2=CHCH2CHO  300 - 2500   2.01E-11              2
  1991TSA221-273   ·CH2CH=CH2 + C2H3C2H4 + CH2=C=CH2  300 - 2500   4.00E-12              2
  1991TSA221-273   ·CH2CH=CH2 + C2H3C2H2 + CH3CH=CH2  300 - 2500   8.00E-12              2
  1991TSA221-273   ·CH2CH=CH2 + CH3CO → CH3C(O)CH2CH=CH2  300 - 2500   3.01E-11              2
  1991TSA221-273   ·CH2CH=CH2 + ·OH → Products  300 - 2500   2.51E-11              2
  1991TSA221-273   ·CH2CH=CH2 + HO2·OH + CH2=CHCH2O  300 - 2500   1.60E-11              2
  1991TSA221-273   ·CH2CH=CH2 + iso-C4H9iso-C4H10 + CH2=C=CH2  300 - 2500   1.30E-12       -549      2
  1991TSA221-273   ·CH2CH=CH2 + iso-C4H9CH3CH=CH2 + iso-C4H8  300 - 2500   1.30E-12       -549      2
  1991TSA221-273   ·CH2CH=CH2 + ·OHCH2=C=CH2 + H2O  300 - 2500   1.00E-11              2
  1991TSA221-273   ·CH2CH=CH2 + iso-C4H91-Hexene, 5-methyl-  300 - 2500   3.40E-11       -549      2
  1991TSA221-273   ·CH2CH=CH2 + H2O2CH3CH=CH2 + HO2  300 - 2500   7.67E-14   2.05   5.68E04      2
  1991TSA221-273   ·CH2CH=CH2 + H2O2CH3CH=CH2 + HO2  300 - 2500   7.67E-14   2.05   5.68E04      2
  1991TSA221-273   ·CH2CH=CH2 + O2CH2=C=CH2 + HO2  300 - 2500   <2.01E-12       5.67E04      2
  1991TSA221-273   ·CH2CH=CH2 + → Products  300 - 2500   3.30E-10              2
  1991TSA221-273   ·CH2CH=CH2 + CH2=C=CH2 + H2  300 - 2500   3.01E-11              2
  1991TSA221-273   ·CH2CH=CH2 + ·C2H5C2H6 + CH2=C=CH2  300 - 2500   1.60E-12       -549      2
  1991TSA221-273   ·CH2CH=CH2 + ·C2H5C2H4 + CH3CH=CH2  300 - 2500   4.30E-12       -549      2
  1991TSA221-273   ·CH2CH=CH2 + CH2=CHCHO +   300 - 2500   1.00E-10              2
  1991TSA221-273   ·CH2CH=CH2 + ·CH21,3-Butadiene +   300 - 2500   5.00E-11              2
  1991TSA221-273   ·CH2CH=CH2 + C2H3 → Products  300 - 2500   8.00E-11              2
  1991TSA221-273   CH3CH=CH2 + ·CH3CH4 + CH3CH=CH  300 - 2500   0.61       3.00E04      2
  Reference reaction:  CH3CH=CH2 + ·CH3CH4 + ·CH2CH=CH2 2
  1991TSA221-273   CH3CH=CH2 + ·CH3CH4 + CH2=C(·)CH3  300 - 2500   0.38       2.50E04      2
  Reference reaction:  CH3CH=CH2 + ·CH3CH4 + ·CH2CH=CH2 2
  1991TSA221-273   CH3CH=CH2 + C2H3C2H4 + CH3CH=CH  300 - 2500   0.61       2.59E04      2
  Reference reaction:  CH3CH=CH2 + C2H3C2H4 + ·CH2CH=CH2 2
  1991TSA221-273   CH3CH=CH2 + C2H3C2H4 + CH2=C(·)CH3  300 - 2500   0.38       2.09E04      2
  Reference reaction:  CH3CH=CH2 + C2H3C2H4 + ·CH2CH=CH2 2
  1991TSA221-273   CH3CH=CH2 + H2 + CH2=C(·)CH3  300 - 2500   2.37       3.06E04      2
  Reference reaction:  CH3CH=CH2 + H2 + ·CH2CH=CH2 2
  1991TSA221-273   CH3CH=CH2 + H2C=C=O + ·CH3 +   300 - 2500   2.00              2
  Reference reaction:  CH3CH=CH2 + CH3CH=C=O + + 2
  1991TSA221-273   ·CH2CH=CH2 + ·C2HC2H2 + CH2=C=CH2  300 - 2500   0.15              2
  Reference reaction:  ·CH2CH=CH2 + ·C2H → Products 2
  1991TSA221-273   ·CH2CH=CH2 + ·C2HC2H3 + CH2=C=CH  300 - 2500   20.00              2
  Reference reaction:  ·CH2CH=CH2 + ·C2H + HC≡CCHCH=CH2 2
  1991TSA221-273   ·CH2CH=CH2 + ·CH21,3-Butadiene +   300 - 2500   4.00              2
  Reference reaction:  ·CH2CH=CH2 + ·CH2C2H4 + C2H3 2
  1991TSA221-273   CH3CH=CH2 + iso-C4H9 → Adduct  300 - 2500   1.69E-13       3.01E04      2
  1991TSA221-273   CH3CH=CH2 + ·OH → Products  300 - 2500   4.85E-12       -4190      2
  1991TSA221-273   CH3CH=CH2 + H2 + CH3CH=CH  300 - 2500   4.65       4.10E04      2
  Reference reaction:  CH3CH=CH2 + H2 + ·CH2CH=CH2 2
  1991TSA221-273   CH3CH=CH2 + n-C3H71-C4H8 + ·C2H5  300 - 2500   1.00       -8314      2
  Reference reaction:  CH3CH=CH2 + n-C3H71-C5H10 + ·CH3 2

Search returned 115 records.