Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Tsang, W.
Title:   Chemical kinetic data base for combustion chemistry. Part V. Propene
Journal:   J. Phys. Chem. Ref. Data
Volume:   20
Page(s):   221 - 273
Year:   1991
Reference type:   Journal article
Squib:   1991TSA221-273

Reaction:   CH3CH=CH2·CH2CH=CH2 +
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   2.5x1015 [s-1] e-362511 [J/mole]/RT
Uncertainty:   3.0
Bath gas:   Products
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 1.91E-48
400 1.15E-32
500 3.37E-23
600 6.91E-17
700 2.23E-12
800 5.36E-9
900 2.28E-6
1000 2.90E-4
1100 1.53E-2
1200 4.16E-1
1300 6.80E0
1400 7.46E1
1500 5.95E2
1600 3.66E3
1700 1.82E4
1800 7.56E4
1900 2.70E5
2000 8.52E5
2100 2.41E6
2200 6.18E6
2300 1.46E7
2400 3.22E7
2500 6.67E7