Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Tsang, W.
Title:   Chemical kinetic data base for combustion chemistry. Part V. Propene
Journal:   J. Phys. Chem. Ref. Data
Volume:   20
Page(s):   221 - 273
Year:   1991
Reference type:   Journal article
Squib:   1991TSA221-273

Reaction:   CH3CH=CH2·CH3 + C2H3
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   1.18x1018 [s-1] (T/298 K)-1.20 e-409072 [J/mole]/RT
Uncertainty:   3.0
Bath gas:   Products
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 6.98E-54
400 3.16E-36
500 1.17E-25
600 1.24E-18
700 1.27E-13
800 7.05E-10
900 5.68E-7
1000 1.18E-4
1100 9.26E-3
1200 3.47E-1
1300 7.38E0
1400 1.01E2
1500 9.66E2
1600 6.94E3
1700 3.94E4
1800 1.84E5
1900 7.25E5
2000 2.49E6
2100 7.57E6
2200 2.08E7
2300 5.21E7
2400 1.21E8
2500 2.61E8