Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Tsang, W.
Title:   Chemical kinetic data base for combustion chemistry. Part V. Propene
Journal:   J. Phys. Chem. Ref. Data
Volume:   20
Page(s):   221 - 273
Year:   1991
Reference type:   Journal article
Squib:   1991TSA221-273

Reaction:   CH3CH=CH2 + 1-C3H71-C4H8 + ·C2H5
Reaction order:   2
Reference reaction:   CH3CH=CH2 + 1-C3H71-C5H10 + ·CH3
Reference reaction order:   2
Temperature:   300 - 2500 K
Rate expression:   1.0 e8314 [J/mole]/RT
Uncertainty:   3.0
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
300 2.80E1
400 1.22E1
500 7.39E0
600 5.29E0
700 4.17E0
800 3.49E0
900 3.04E0
1000 2.72E0
1100 2.48E0
1200 2.30E0
1300 2.16E0
1400 2.04E0
1500 1.95E0
1600 1.87E0
1700 1.80E0
1800 1.74E0
1900 1.69E0
2000 1.65E0
2100 1.61E0
2200 1.58E0
2300 1.54E0
2400 1.52E0
2500 1.49E0