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Accessibility information
Author(s):   Baggott, J.E.; Blitz, M.A.; Frey, H.M.; Lightfoot, P.D.; Walsh, R.
Title:   Time resolved kinetic studies of the gas-phase reactions of dimethylsilylene with some O-donor molecules: Part I. Room temperature studies
Journal:   Int. J. Chem. Kinet.
Volume:   24
Page(s):   127 - 143
Year:   1992
Reference type:   Journal article
Squib:   1992BAG/BLI127-143

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1992BAG/BLI127-143   CH3OH + (CH3)2Si → Products  295   1.18E-12              2
  1992BAG/BLI127-143   Oxirane + (CH3)2SiC2H4 + (CH3)2Si=O  295   3.89E-12              2
  1992BAG/BLI127-143   Tetrahydrofuran + (CH3)2Si → Products  295   3.92E-12              2
  1992BAG/BLI127-143   Oxetane + (CH3)2Si → Products  295   3.34E-11              2
  1992BAG/BLI127-143   CO + (CH3)2Si → Products  295   <5.00E-14              2
  1992BAG/BLI127-143   CH3OD + (CH3)2Si → Products  295   1.03E-12              2
  1992BAG/BLI127-143   (CH3)2Si + 3,3-dimethyl-oxetane → Products  295   4.67E-11              2
  1992BAG/BLI127-143   (CH3)2Si + H2O → Products  295   1.20E-13              2
  1992BAG/BLI127-143   (CH3)2Si + O2 → Products  295   2.51E-13              2
  1992BAG/BLI127-143   (CH3)2Si + D2O → Products  295   7.69E-14              2

Search returned 10 records.