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Author(s):   Chen, J.; Zhu, T.; Niki, H.
Title:   Long path FTIR spectroscopic study of the reactions of CF3O radicals with ethane and propane
Journal:   Geophys. Res. Lett.
Volume:   19
Page(s):   2215 - 2218
Year:   1992
Reference type:   Journal article
Squib:   1992CHE/ZHU2215-2218

Reaction:   CH4 + CF3O → CF3OH + ·CH3
Reaction order:   2
Reference reaction:   NO + CF3OCOF2 + FNO
Temperature:   297 K
Pressure:  0.93 bar
Rate expression:   2.01x10-15 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Fourier transform (FTIR)

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