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Accessibility information
Author(s):   Emdee, J.L.; Brezinsky, K.; Glassman, I.
Title:   A kinetic model for the oxidation of toluene near 1200 K
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   2151 - 2161
Year:   1992
Reference type:   Journal article
Squib:   1992EMD/BRE2151-2161

Reaction:   O2 + HCCO → Products
Reaction order:   2
Temperature:   300 - 1500 K
Rate expression:   2.42x10-12 [cm3/molecule s] e-10460 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Comments:   Estimated value. Assumed products CO + CO + OH

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 3.66E-14
400 1.04E-13
500 1.96E-13
600 2.98E-13
700 4.02E-13
800 5.03E-13
900 5.99E-13
1000 6.89E-13
1100 7.73E-13
1200 8.50E-13
1300 9.21E-13
1400 9.87E-13
1500 1.05E-12