Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Lifshitz, A.; Wohlfeiler, D.
Title:   Thermal decomposition of isoxazole. Experimental and modeling study
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   4505 - 4515
Year:   1992
Reference type:   Journal article
Squib:   1992LIF/WOH4505-4515

Reaction:   IsooxazoleCH3CN + CO
Reaction order:   1
Temperature:   850 - 1100 K
Pressure:  0.11 - 0.16 bar
Rate expression:   7.24x1011 [s-1] e-183750 [J/mole]/RT
Bath gas:   Isooxazole
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
850 3.70E0
875 7.78E0
900 1.57E1
925 3.05E1
950 5.71E1
975 1.04E2
1000 1.83E2
1025 3.13E2
1050 5.23E2
1075 8.54E2
1100 1.36E3