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Author(s):   Lifshitz, A.; Wohlfeiler, D.
Title:   Thermal decomposition of 5-methylisoxazole. Experimental and modeling study
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   7367 - 7375
Year:   1992
Reference type:   Journal article
Squib:   1992LIF/WOH7367-7375

Reaction:   Isoxazole, 5-methyl-CH3CN + H2C=C=O
Reaction order:   1
Temperature:   850 - 1080 K
Pressure:  0.11 - 0.16 bar
Rate expression:   4.18x1017 [s-1] e-311793 [J/mole]/RT
Bath gas:   Isoxazole, 5-methyl-
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
850 2.89E-2
875 1.02E-1
900 3.35E-1
925 1.03E0
950 3.01E0
975 8.27E0
1000 2.16E1
1025 5.40E1
1050 1.29E2
1075 2.96E2
1080 3.48E2