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Author(s):   Markwalder, B.; Gozel, P.; van den Bergh, H.
Title:   Temperature-jump measurements on the kinetics of association and dissociation in weakly bound systems: N2O4+M=NO2+NO2+M
Journal:   J. Chem. Phys.
Volume:   97
Page(s):   5472 - 5479
Year:   1992
Reference type:   Journal article
Squib:   1992MAR/GOZ5472-5479

Reaction:   N2O4NO2 + NO2
Reaction order:   1
Temperature:   255 - 273 K
Pressure:  0.30 - 200 bar
Rate expression:   4.61x1016 [±5.1x1015 s-1] (T/298 K)(1.30±0.20) e-56455 [±5646 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
255 1.03E5
273 6.49E5