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Accessibility information
Author(s):   Miller, J.A.; Melius, C.F.
Title:   Kinetic and Thermodynamic Issues in the Formation of Aromatic Compounds in Flames of Aliphatic Fuels
Journal:   Combust. Flame
Volume:   91
Page(s):   21 - 39
Year:   1992
Reference type:   Journal article
Squib:   1992MIL/MEL21-39

Reaction:   O2 + HCCO → Products
Reaction order:   2
Temperature:   300 - 1500 K
Rate expression:   6.93x10-13 [cm3/molecule s] (T/298 K)1.00
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Comments:   Estimated extrapolation to high temperatures consistent with lower temperature measurements. Products assigned as CO2 + CO + H (HCO dissociates immediately to CO+H).

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 6.97E-13
400 9.30E-13
500 1.16E-12
600 1.39E-12
700 1.63E-12
800 1.86E-12
900 2.09E-12
1000 2.32E-12
1100 2.56E-12
1200 2.79E-12
1300 3.02E-12
1400 3.25E-12
1500 3.49E-12