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Author(s):   Nielsen, O.J.; Ellermann, T.; Bartkiewicz, E.; Wallington, T.J.; Hurley, M.D.
Title:   UV absorption spectra, kinetics and mechanisms of the self-reaction of CHF2O2 radicals in the gas phase at 298 K
Journal:   Chem. Phys. Lett.
Volume:   192
Page(s):   82 - 88
Year:   1992
Reference type:   Journal article
Squib:   1992NIE/ELL82-88

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1992NIE/ELL82-88   CH2F2 + ·F·CHF2 + HF  298   9.80E-12           9.80E-12  2
  1992NIE/ELL82-88   CH2F2 + ·F·CHF2 + HF  298   70.00           70.00  2
  Reference reaction:  O2 + ·FO2F 2
  1992NIE/ELL82-88   CH2F2 + ·Cl·CHF2 + HCl  295   3.20E-14              2
  1992NIE/ELL82-88   CH2F2 + ·Cl·CHF2 + HCl  295   0.32              2
  Reference reaction:  CH4 + ·Cl·CH3 + HCl 2
  1992NIE/ELL82-88   CHF2OO + CHF2OO → Products  298   5.00E-12           5.00E-12  2

Search returned 5 records.