Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Nielsen, O.J.; Ellermann, T.; Bartkiewicz, E.; Wallington, T.J.; Hurley, M.D.
Title:   UV absorption spectra, kinetics and mechanisms of the self-reaction of CHF2O2 radicals in the gas phase at 298 K
Journal:   Chem. Phys. Lett.
Volume:   192
Page(s):   82 - 88
Year:   1992
Reference type:   Journal article
Squib:   1992NIE/ELL82-88

Reaction:   CH2F2 + ·F·CHF2 + HF
Reaction order:   2
Reference reaction:   O2 + ·FO2F
Temperature:   298 K
Pressure:  0.15 - 0.95 bar
Rate expression:   9.8x10-12 [±3.16x10-12 cm3/molecule s]
Bath gas:   SF6
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.