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Title: A comparison between the oxidation reactions of the alkali and alkaline earth atoms
Page(s): 29 - 56
Year: 1992
Book Title: Gas-Phase Metal Reactions,
Publisher: ed. A. Fontijn
Publisher address: pub. Elsevier Science Publ., Amsterdam, Netherlands
Reference type: Book Chapter
Squib: 1992PLA29-56C
Reaction:
Ba + N2O → BaO + N2
Reaction order:
2
Temperature:
242 - 850
K
Pressure: 5.33E-3 - 0.13 bar
Rate expression:
3.01x10-10 [±8.97x10-12 cm3/molecule s] e-5695 [±228 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Laser induced fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 242 | 1.77E-11 |
| 250 | 1.94E-11 |
| 300 | 3.06E-11 |
| 350 | 4.25E-11 |
| 400 | 5.42E-11 |
| 450 | 6.56E-11 |
| 500 | 7.64E-11 |
| 550 | 8.65E-11 |
| 600 | 9.60E-11 |
| 650 | 1.05E-10 |
| 700 | 1.13E-10 |
| 750 | 1.21E-10 |
| 800 | 1.28E-10 |
| 850 | 1.34E-10 |