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Accessibility information
Author(s):   Senkan, S.M.; Quam, D.
Title:   Correlation of reaction rate coefficients for the abstraction of hydrogen atoms from organic compounds by chlorine radical attack
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   10837 - 10842
Year:   1992
Reference type:   Journal article
Squib:   1992SEN/QUA10837-10842

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1992SEN/QUA10837-10842   CH3OH + ·Cl(·)CH2OH + HCl  300 - 400   3.72E-11       -1563      2
  1992SEN/QUA10837-10842   CHCl3 + ·Cl·CCl3 + HCl  300 - 400   9.55E-12       1.11E04      2
  1992SEN/QUA10837-10842   CH3CCl3 + ·ClHCl + CCl3CH2  300 - 400   3.77E-11       1.75E04      2
  1992SEN/QUA10837-10842   CH3Br + ·ClHCl + ·CH2Br  300 - 400   3.72E-11       1.06E04      2
  1992SEN/QUA10837-10842   C2H6 + ·Cl·C2H5 + HCl  300 - 400   3.70E-11       4914      2
  1992SEN/QUA10837-10842   CH3Cl + ·Cl·CH2Cl + HCl  300 - 400   3.70E-11       1.12E04      2
  1992SEN/QUA10837-10842   CH2Br2 + ·ClHCl + CHBr2  300 - 400   2.89E-11       9312      2
  1992SEN/QUA10837-10842   CH2ClBr + ·ClHCl + ·CHBrCl  300 - 400   2.86E-11       9977      2
  1992SEN/QUA10837-10842   C2H5Cl + ·ClHCl + CH2CH2Cl  300 - 400   3.74E-11       9645      2
  1992SEN/QUA10837-10842   C2H5Cl + ·ClHCl + CH3CHCl  300 - 400   2.86E-11       4348      2
  1992SEN/QUA10837-10842   CH2Cl2 + ·ClCHCl2 + HCl  300 - 400   2.87E-11       1.07E04      2
  1992SEN/QUA10837-10842   CH2F2 + ·Cl·CHF2 + HCl  300 - 400   2.86E-11       1.30E04      2
  1992SEN/QUA10837-10842   CH3CHCl2 + ·ClHCl + CH3CCl2·  300 - 400   9.53E-12       4739      2
  1992SEN/QUA10837-10842   CH3CHCl2 + ·ClHCl + CHCl2CH2·  300 - 400   3.72E-11       1.50E04      2
  1992SEN/QUA10837-10842   CH3CHF2 + ·ClHCl + CH3CF2  300 - 400   9.60E-12       7076      2
  1992SEN/QUA10837-10842   CH3CHF2 + ·ClHCl + CH2CHF2  300 - 400   3.72E-11       1.93E04      2
  1992SEN/QUA10837-10842   CHCl2CCl3 + ·Cl → C2Cl5 + HCl  300 - 400   9.60E-12       1.73E04      2
  1992SEN/QUA10837-10842   CHCl2CH2Cl + ·ClHCl + CHCl2CHCl  300 - 400   2.89E-11       1.46E04      2
  1992SEN/QUA10837-10842   CHCl2CH2Cl + ·ClHCl + CH2ClCCl2·  300 - 400   9.53E-12       9395      2
  1992SEN/QUA10837-10842   (CHCl2)2 + ·ClHCl + CHCl2C(·)Cl2  300 - 400   9.60E-12       1.49E04      2
  1992SEN/QUA10837-10842   CH2ClCH2Cl + ·ClHCl + CH2ClCHCl·  300 - 400   2.89E-11       9063      2
  1992SEN/QUA10837-10842   (CH3)2O + ·ClHCl + CH3OCH2·  300 - 400   3.75E-11       -4515      2
  1992SEN/QUA10837-10842   C2H5F + ·ClHCl + CH2CH2F  300 - 400   3.74E-11       9811      2
  1992SEN/QUA10837-10842   C2H5F + ·ClHCl + CH3C(·)HF  300 - 400   2.89E-11       5554      2
  1992SEN/QUA10837-10842   CHF2CHF2 + ·ClHCl + CHF2CF2  300 - 400   9.65E-12       2.15E04      2
  1992SEN/QUA10837-10842   CH3CF3 + ·ClCF3CH2 + HCl  300 - 400   3.70E-11       3.54E04      2
  1992SEN/QUA10837-10842   CH2FCHF2 + ·ClHCl + CH2FC(·)F2  300 - 400   9.53E-12       1.20E04      2
  1992SEN/QUA10837-10842   CH2FCHF2 + ·ClHCl + CHF2C(·)HF  300 - 400   2.87E-11       1.99E04      2
  1992SEN/QUA10837-10842   CH3F + ·Cl·CH2F + HCl  300 - 400   3.69E-11       1.24E04      2
  1992SEN/QUA10837-10842   CH2FCl + ·ClHCl + ·CClFH  300 - 400   2.87E-11       1.19E04      2
  1992SEN/QUA10837-10842   CH2FCH2F + ·ClHCl + CH2FCHF  300 - 400   2.87E-11       1.04E04      2
  1992SEN/QUA10837-10842   CH2ClCCl3 + ·ClHCl + CCl3CHCl  300 - 400   2.82E-11       1.69E04      2
  1992SEN/QUA10837-10842   (CH3O)2 + ·Cl → ·CH2OOCH3 + HCl  300 - 400   3.72E-11       -3434      2

Search returned 33 records.