Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Stothard, N.D.; Walker, R.W.
Title:   Oxidation chemistry of propene in the autoignition region: arrhenius parameters for the allyl + O2 reaction pathways and kinetics data for initiation reactions
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   88
Page(s):   2621 - 2629
Year:   1992
Reference type:   Journal article
Squib:   1992STO/WAL2621-2629

Reaction:   ·CH2CH=CH2 + O2 → Other Products + CO
Reaction order:   2
Reference reaction:   ·CH2CH=CH2 + ·CH2CH=CH2CH2=CHCH2CH2CH=CH2
Temperature:   673 - 793 K
Pressure:  6.40E-2 - 0.67 bar
Rate expression:   7.59x10-12 [cm3/molecule s] e-78572 [±4714 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
673 6.05E-18
675 6.31E-18
700 1.04E-17
725 1.66E-17
750 2.56E-17
775 3.84E-17
793 5.07E-17