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Accessibility information
Author(s):   Tsang, W.; Walker, J.A.
Title:   Pyrolysis of 1,7-octadiene and the kinetic and thermodynamic stability of allyl and 4-pentenyl radicals
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   8378 - 8384
Year:   1992
Reference type:   Journal article
Squib:   1992TSA/WAL8378-8384

Reaction:   CH2=CHCH2CH2CH2· → Cyclopentene +
Reaction order:   1
Reference reaction:   CH2=CHCH2CH2CH2· → C2H4 + ·CH2CH=CH2
Reference reaction order:   1
Temperature:   1040 - 1200 K
Pressure:  2.03 - 7.09 bar
Rate expression:   6.9x10-3±4.0x10-3 e17627 [±4224 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
1040 5.30E-2
1050 5.20E-2
1075 4.96E-2
1100 4.74E-2
1125 4.54E-2
1150 4.36E-2
1175 4.19E-2
1200 4.04E-2