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Accessibility information
Author(s):   Tsang, W.
Title:   Chemical kinetic data base for propellant combustion. II. Reactions involving CN, NCO, and HNCO
Journal:   J. Phys. Chem. Ref. Data
Volume:   21
Page(s):   753 - 791
Year:   1992
Reference type:   Journal article
Squib:   1992TSA753-791

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1992TSA753-791   CH2O + CNHCN + HCO  500 - 2500   7.01E-11              2
  1992TSA753-791   CH2O + NCOHN=C=O + HCO  500 - 2500   1.00E-11              2
  1992TSA753-791   CNC + N  500 - 2500   4.20E-10       5.90E05      2
  1992TSA753-791   CNC + N  500 - 2500   6.29E-10       5.90E05      2
  1992TSA753-791   CNC + N  500 - 2500   1.00E-09       5.90E05      2
  1992TSA753-791   CN + CNNCCN  500 - 2500   9.40E-12              2
  1992TSA753-791   CN + CNNCCN  500 - 2500   3.28E-29   -2.61          3
  1992TSA753-791   CN + CNNCCN  500 - 2500   4.94E-29   -2.62          3
  1992TSA753-791   CN + HCNNCCN +   500 - 2500   4.25E-13   1.71   6402      2
  1992TSA753-791   CN + HN=C=OHCN + NCO  500 - 2500   2.51E-11              2
  1992TSA753-791   CN + H2HCN +   500 - 2500   4.10E-12   1.55   1.26E04      2
  1992TSA753-791   CN + HCOHCN + CO  500 - 2500   1.00E-10              2
  1992TSA753-791   CN + ·OHHCN +   500 - 2500   1.00E-11       8314      2
  1992TSA753-791   CN + ·OH + NCO  500 - 2500   7.01E-11              2
  1992TSA753-791   CN + H2OHCN + ·OH  500 - 2500   1.30E-11       3.13E04      2
  1992TSA753-791   CN + HNO2HCN + NO2  500 - 2500   2.01E-11              2
  1992TSA753-791   CN + N2OCNN + NO  500 - 2500   1.73E-14   2.60   1.55E04      2
  1992TSA753-791   CN + NOONCN  500 - 2500   6.59E-11              2
  1992TSA753-791   CN + NOONCN  500 - 2500   1.35E-27   -5.40   1.84E04      3
  1992TSA753-791   CN + NOONCN  500 - 2500   1.97E-27   -6.20   2.05E04      3
  1992TSA753-791   CN + NON + NCO  500 - 2500   1.60E-10       1.76E05      2
  1992TSA753-791   CN + NO2NO + NCO  500 - 2500   4.00E-11       -1546      2
  1992TSA753-791   CN + HCN  500 - 2500   1.73E-10   -0.50          2
  1992TSA753-791   CN + HCN  500 - 2500   8.63E-30   -2.20   4714      3
  1992TSA753-791   CN + HCN  500 - 2500   9.35E-30   -2.00   4332      3
  1992TSA753-791   CN + HNOHCN + NO  500 - 2500   3.01E-11              2
  1992TSA753-791   CN + CO + N  500 - 2500   3.40E-11       1746      2
  1992TSA753-791   CN + NCOCO + CNN  500 - 2500   3.01E-11              2
  1992TSA753-791   HCN + NCOCN + HN=C=O  500 - 2500   2.01E-11       3.71E04      2
  1992TSA753-791   HN=C=OCO + NH  500 - 2500   6.00E13       4.17E05      1
  1992TSA753-791   HN=C=OCO + NH  500 - 2500   7.69E-04   -3.10   4.27E05      2
  1992TSA753-791   HN=C=OCO + NH  500 - 2500   1.38E-03   -3.06   4.26E05      2
  1992TSA753-791   HN=C=O + HN=C=OCO2 + CH2N2  500 - 2500   1.10E-13       1.76E05      2
  1992TSA753-791   HN=C=O + HCOCH2O + NCO  500 - 2500   5.00E-12       1.09E05      2
  1992TSA753-791   HN=C=O + ·OHH2O + NCO  500 - 2500   9.43E-14   2.00   1.07E04      2
  1992TSA753-791   HN=C=O + CO + NH2  500 - 2500   5.00E-11       1.91E04      2
  1992TSA753-791   HN=C=O + H2 + NCO  500 - 2500   1.44E-12   1.81   6.93E04      2
  1992TSA753-791   HN=C=O + CO2 + NH  500 - 2500   4.93E-13   1.41   3.57E04      2
  1992TSA753-791   HN=C=O + ·OH + NCO  500 - 2500   6.16E-13   2.11   4.78E04      2
  1992TSA753-791   H2 + NCOHN=C=O +   500 - 2500   3.06E-13   2.00   2.52E04      2
  1992TSA753-791   HCO + NCOHN=C=O + CO  500 - 2500   5.99E-11              2
  1992TSA753-791   ·OH + NCO → Adduct  500 - 2500   1.69E-11              2
  1992TSA753-791   ·OH + NCO → Adduct  500 - 2500   3.14E-27   -5.96   1.48E04      3
  1992TSA753-791   ·OH + NCO → Adduct  500 - 2500   4.30E-27   -5.77   1.38E04      3
  1992TSA753-791   ·OH + NCOHN=C=O +   500 - 2500   5.38E-14   2.27   -4132      2
  1992TSA753-791   H2O + NCOHN=C=O + ·OH  500 - 2500   9.13E-14   2.17   2.54E04      2
  1992TSA753-791   HNO2 + NCOHN=C=O + NO2  500 - 2500   5.99E-12              2
  1992TSA753-791   N2O + NCOCO + N2 + NO  500 - 2500   <1.50E-10       1.16E05      2
  1992TSA753-791   NO + NCO → Products  500 - 2500   1.69E-11       -1630      2
  1992TSA753-791   NO + NCOCO2 + N2  500 - 2500   0.44              2
  Reference reaction:  NO + NCO → Products 2
  1992TSA753-791   NO + NCOCO + N2 +   500 - 2500   0.23              2
  Reference reaction:  NO + NCO → Products 2
  1992TSA753-791   NO + NCOCO + N2O  500 - 2500   0.33              2
  Reference reaction:  NO + NCO → Products 2
  1992TSA753-791   NO2 + NCO → Products  500 - 2500   3.01E-11              2
  1992TSA753-791   NO2 + NCOCO2 + N2O  500 - 2500   0.30              2
  Reference reaction:  NO2 + NCOCO + NO + NO 2
  1992TSA753-791   + NCOHCN +   500 - 2500   1.86E-11   0.90   2.43E04      2
  1992TSA753-791   + NCOCO + NH  500 - 2500   8.90E-11              2
  1992TSA753-791   HNO + NCOHN=C=O + NO  500 - 2500   3.01E-11              2
  1992TSA753-791   + NCOCN + O2  500 - 2500   4.05E-10   -1.43   2.91E04      2
  1992TSA753-791   + NCOCO + NO  500 - 2500   7.51E-11              2
  1992TSA753-791   NCOCO + N  1800 - 2500   2.84E-06   -1.95   2.51E05      2
  1992TSA753-791   NCOCO + N  1800 - 2500   3.95E-06   -1.91   2.50E05      2
  1992TSA753-791   NCO + NCOCO + CO + N2  500 - 2500   3.01E-11              2

Search returned 62 records.