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Accessibility information
Author(s):   Wallington, T.J.; Andino, J.M.; Potts, A.R.
Title:   Pulse radiolysis and fourier transform infrared study of neopentyl peroxy radicals in the gas phase at 297 K
Journal:   Int. J. Chem. Kinet.
Volume:   24
Page(s):   649 - 663
Year:   1992
Reference type:   Journal article
Squib:   1992WAL/AND649-663

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1992WAL/AND649-663   tert-C4H9 + O2(CH3)3CO2  298   3.01E-12           3.01E-12  2
  1992WAL/AND649-663   (CH3)3CCH2OO + (CH3)3CCH2OO → Products  298   1.07E-12           1.07E-12  2
  1992WAL/AND649-663   (CH3)3CCH2OO + (CH3)3CCH2OO → (CH3)3CCH2OH + 2,2-dimethylpropanal + O2  298   5.99E-13           5.99E-13  2
  1992WAL/AND649-663   (CH3)3CCH2OO + (CH3)3CCH2OO → O2 + (CH3)3CCH2O· + (CH3)3CCH2  298   4.00E-13           4.00E-13  2
  1992WAL/AND649-663   (CH3)3CCH2OO + (CH3)3CCH2OO → O2 + (CH3)3CCH2O· + (CH3)3CCH2  298   0.39           0.39  2
  Reference reaction:  (CH3)3CCH2OO + (CH3)3CCH2OO → Products 2
  1992WAL/AND649-663   (CH3)3CCH2O· → CH2O + tert-C4H9  298   >2.50E05           2.50E05  1

Search returned 6 records.