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Accessibility information
Author(s):   Zhang, Z.; Saini, R.D.; Kurylo, M.J.; Huie, R.E.
Title:   A temperature dependent kinetic study of the reaction of the hydroxyl radical with CH3Br
Journal:   Geophys. Res. Lett.
Volume:   19
Page(s):   2413 - 2416
Year:   1992
Reference type:   Journal article
Squib:   1992ZHA/SAI2413-2416

Reaction:   CH3Br + ·OHH2O + ·CH2Br
Reaction order:   2
Temperature:   250 - 400 K
Pressure:  4.67E-2 bar
Rate expression:   5.78x10-12 [cm3/molecule s] e-12971 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
250 1.13E-14
275 1.99E-14
300 3.19E-14
325 4.76E-14
350 6.70E-14
375 9.02E-14
400 1.17E-13