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Accessibility information
Author(s):   Ashworth, A.; Harrison, P.G.
Title:   Fourier-transform infrared study of the gas-phase thermolysis of trifluoroacetic acid
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   89
Page(s):   2409 - 2412
Year:   1993
Reference type:   Journal article
Squib:   1993ASH/HAR2409-2412

Reaction:   CF3COOHCHF3 + CO2
Reaction order:   1
Temperature:   573 - 643 K
Pressure:  1.11E-2 bar
Rate expression:   1.78x108 [s-1] e-113908 [±6843 J/mole]/RT
Uncertainty:   1.22000003
Bath gas:   CF3COOH
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
573 7.36E-3
575 8.00E-3
600 2.16E-2
625 5.38E-2
643 9.94E-2