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Accessibility information
Author(s):   Campbell, M.L.; McClean, R.E.
Title:   Kinetics of neutral transition-metal atoms in the gas phase: oxidation reactions of Ti(a3F) from 300 to 600 K
Journal:   J. Phys. Chem.
Volume:   97
Page(s):   7942 - 7946
Year:   1993
Reference type:   Journal article
Squib:   1993CAM/MCC7942-7946

Reaction:   Ti + SO2 → Products
Reaction order:   2
Temperature:   295 - 597 K
Pressure:  2.67E-2 bar
Rate expression:   1.69x10-10 [±3.16x10-11 cm3/molecule s] e-2652 [±637 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
295 5.74E-11
300 5.85E-11
325 6.35E-11
350 6.81E-11
375 7.23E-11
400 7.63E-11
425 8.00E-11
450 8.34E-11
475 8.65E-11
500 8.95E-11
525 9.22E-11
550 9.48E-11
575 9.73E-11
597 9.93E-11