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Accessibility information
Author(s):   Chuchani, G.; Martin, I.; Rotinov, A.; Dominguez, R.M.
Title:   Elimination kinetics and mechanism of primary, secondary and tertiary α-hydroxycarboxylic acids in the gas phase
Journal:   J. Phys. Org. Chem.
Volume:   6
Page(s):   54 - 58
Year:   1993
Reference type:   Journal article
Squib:   1993CHU/MAR54-58

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1993CHU/MAR54-58   Propanoic acid, 2-hydroxy-CH3CHO + CO + H2O  603 - 653   1.74E12       1.83E05      1
  1993CHU/MAR54-58   HOCH2COOHCH2O + CO + H2O  614 - 663   1.07E14       2.10E05      1
  1993CHU/MAR54-58   (CH3)2COHCOOHAcetone + CO + H2O  553 - 603   8.13E12       1.75E05      1

Search returned 3 records.