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Accessibility information
Author(s):   Dunlop, J.R.; Tully, F.P.
Title:   Catalytic dehydration of alcohols by OH. 2-propanol: an intermediate case
Journal:   J. Phys. Chem.
Volume:   97
Page(s):   6457 - 6464
Year:   1993
Reference type:   Journal article
Squib:   1993DUN/TUL6457-6464

Reaction:   iso-C3H7OH + ·OH → Other Products + H2O
Reaction order:   2
Temperature:   293 - 745 K
Pressure:  1.00 bar
Rate expression:   4.18x10-13 [cm3/molecule s] (T/298 K)1.86 e6119 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
293 5.00E-12
300 4.93E-12
325 4.73E-12
350 4.62E-12
375 4.57E-12
400 4.56E-12
425 4.58E-12
450 4.62E-12
475 4.69E-12
500 4.77E-12
525 4.87E-12
550 4.99E-12
575 5.11E-12
600 5.24E-12
625 5.39E-12
650 5.54E-12
675 5.70E-12
700 5.86E-12
725 6.04E-12
745 6.18E-12