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Author(s):   Fenter, F.F.; Lightfoot, P.D.; Caralp, F.; Lesclaux, R.; Niiranen, J.T.; Gutman, D.
Title:   Kinetics of the CHCl2 and CH2Cl association reactions with molecular oxygen between 298 and 448 K and from 1 to 760 torr of total pressure
Journal:   J. Phys. Chem.
Volume:   97
Page(s):   4695 - 4703
Year:   1993
Reference type:   Journal article
Squib:   1993FEN/LIG4695-4703

Reaction:   ·CH2Cl + O2 → CH2ClO2
Reaction order:   2
Temperature:   298 - 448 K
Pressure:  2.67E-2 - 1.01 bar
Rate expression:   2.91x10-12 [±1.99x10-13 cm3/molecule s] (T/298 K)(-1.20±0.40)
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.91E-12
300 2.88E-12
325 2.62E-12
350 2.40E-12
375 2.21E-12
400 2.04E-12
425 1.90E-12
448 1.78E-12