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Author(s):   Hidaka, Y.; Higashihara, T.; Ninomiya, N.; Oshita, H.; Kawano, H.
Title:   Thermal isomerization and decomposition of 2-butyne in shock waves
Journal:   J. Phys. Chem.
Volume:   97
Page(s):   10977 - 10983
Year:   1993
Reference type:   Journal article
Squib:   1993HID/HIG10977-10983

Reaction:   1,3-Butadiene + CH2=CHCH=CH·
Reaction order:   1
Temperature:   1100 - 1600 K
Rate expression:   7.0x1014 [s-1] e-397432 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 9.40E-5
1150 6.22E-4
1200 3.51E-3
1250 1.73E-2
1300 7.52E-2
1350 2.94E-1
1400 1.04E0
1450 3.38E0
1500 1.01E1
1550 2.83E1
1600 7.42E1