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Accessibility information
Author(s):   Hidaka, Y.; Higashihara, T.; Ninomiya, N.; Oshita, H.; Kawano, H.
Title:   Thermal isomerization and decomposition of 2-butyne in shock waves
Journal:   J. Phys. Chem.
Volume:   97
Page(s):   10977 - 10983
Year:   1993
Reference type:   Journal article
Squib:   1993HID/HIG10977-10983

Reaction:   CH3CCCH31,3-Butadiene
Reaction order:   1
Temperature:   1100 - 1600 K
Rate expression:   3.0x1013 [s-1] e-271883 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 3.69E0
1150 1.34E1
1200 4.39E1
1250 1.31E2
1300 3.57E2
1350 9.07E2
1400 2.15E3
1450 4.82E3
1500 1.02E4
1550 2.06E4
1600 3.99E4