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Accessibility information
Author(s):   Kelly, C.; Treacy, J.; Sidebottom, H.W.; Nielsen, O.J.
Title:   Rate constants for the reaction of CF3O radicals with hydrocarbons at 298 K
Journal:   Chem. Phys. Lett.
Volume:   207
Page(s):   498 - 503
Year:   1993
Reference type:   Journal article
Squib:   1993KEL/TRE498-503

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1993KEL/TRE498-503   Benzene + CF3O → CF3OH + Phenyl  298   3.60E-11           3.60E-11  2
  1993KEL/TRE498-503   Benzene + CF3O → CF3OH + Phenyl  298   30.00           30.00  2
  Reference reaction:  C2H6 + CF3O → CF3OH + ·C2H5 2
  1993KEL/TRE498-503   CH4 + CF3O → CF3OH + ·CH3  298   1.20E-14           1.20E-14  2
  1993KEL/TRE498-503   CH4 + CF3O → CF3OH + ·CH3  298   0.01           0.01  2
  Reference reaction:  C2H6 + CF3O → CF3OH + ·C2H5 2
  1993KEL/TRE498-503   C2H4 + CF3O → CF3OH + C2H3  298   3.01E-11           3.01E-11  2
  1993KEL/TRE498-503   C2H4 + CF3O → CF3OH + C2H3  298   25.00           25.00  2
  Reference reaction:  C2H6 + CF3O → CF3OH + ·C2H5 2
  1993KEL/TRE498-503   C3H8 + CF3O → Other Products + CF3OH  298   4.70E-12           4.70E-12  2
  1993KEL/TRE498-503   C3H8 + CF3O → Other Products + CF3OH  298   3.90           3.90  2
  Reference reaction:  C2H6 + CF3O → CF3OH + ·C2H5 2
  1993KEL/TRE498-503   Cyclopropane + CF3O → CF3OH + Cyclopropyl  298   3.60E-13           3.60E-13  2
  1993KEL/TRE498-503   Cyclopropane + CF3O → CF3OH + Cyclopropyl  298   0.30           0.30  2
  Reference reaction:  C2H6 + CF3O → CF3OH + ·C2H5 2
  1993KEL/TRE498-503   iso-C4H10 + CF3O → Other Products + CF3OH  298   7.21E-12           7.21E-12  2
  1993KEL/TRE498-503   iso-C4H10 + CF3O → Other Products + CF3OH  298   6.00           6.00  2
  Reference reaction:  C2H6 + CF3O → CF3OH + ·C2H5 2

Search returned 12 records.