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Accessibility information
Author(s):   Kiefer, J.H.; Kumaran, S.S.; Sundaram, S.
Title:   Vibrational relaxation, dissociation, and dissociation incubation times in norbornene
Journal:   J. Chem. Phys.
Volume:   99
Page(s):   3531 - 3541
Year:   1993
Reference type:   Journal article
Squib:   1993KIE/KUM3531-3541

Reaction:   Bicyclo[2.2.1]hept-2-eneC2H4 + Cyclopentadiene
Reaction order:   1
Temperature:   500 - 1300 K
Pressure:  4.53E-2 - 0.55 bar
Rate expression:   1.05x1015 [s-1] e-193727 [J/mole]/RT
Bath gas:   Kr
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Laser schlieren

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
500 6.07E-6
550 4.20E-4
600 1.43E-2
650 2.84E-1
700 3.68E0
750 3.38E1
800 2.36E2
850 1.31E3
900 5.99E3
950 2.34E4
1000 7.98E4
1050 2.42E5
1100 6.64E5
1150 1.67E6
1200 3.88E6
1250 8.43E6
1300 1.73E7