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Author(s):   Lim, K.P.; Michael, J.V.
Title:   The thermal decomposition of CH3Cl using the Cl-atom absorption method and the bimolecular rate constant for O + CH3 (1609-2002 K) with a pyrolysis photolysis-shock tube technique
Journal:   J. Chem. Phys.
Volume:   98
Page(s):   3919 - 3928
Year:   1993
Reference type:   Journal article
Squib:   1993LIM/MIC3919-3928

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1993LIM/MIC3919-3928   CH3Cl → ·CH3 + ·Cl  1660 - 2060   1.40E15       3.44E05      1
  1993LIM/MIC3919-3928   CH3Cl → ·CH3 + ·Cl  1660 - 2060   1.21E10       2.31E05      1
  1993LIM/MIC3919-3928   ·CH3 + O· → Products  1610 - 2000   1.40E-10              2
Search returned 3 records.