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Accessibility information
Author(s):   Lim, K.P.; Michael, J.V.
Title:   The thermal decomposition of CH3Cl using the Cl-atom absorption method and the bimolecular rate constant for O + CH3 (1609-2002 K) with a pyrolysis photolysis-shock tube technique
Journal:   J. Chem. Phys.
Volume:   98
Page(s):   3919 - 3928
Year:   1993
Reference type:   Journal article
Squib:   1993LIM/MIC3919-3928

Reaction:   CH3Cl·CH3 + ·Cl
Reaction order:   1
Temperature:   1660 - 2060 K
Pressure:  0.80 bar
Rate expression:   1.4x1015 [s-1] e-344219 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1660 2.07E4
1675 2.58E4
1700 3.71E4
1725 5.29E4
1750 7.45E4
1775 1.04E5
1800 1.44E5
1825 1.97E5
1850 2.67E5
1875 3.61E5
1900 4.82E5
1925 6.40E5
1950 8.43E5
1975 1.10E6
2000 1.43E6
2025 1.85E6
2050 2.37E6
2060 2.62E6