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Accessibility information
Author(s):   Lim, K.P.; Michael, J.V.
Title:   The thermal decomposition of CH3Cl using the Cl-atom absorption method and the bimolecular rate constant for O + CH3 (1609-2002 K) with a pyrolysis photolysis-shock tube technique
Journal:   J. Chem. Phys.
Volume:   98
Page(s):   3919 - 3928
Year:   1993
Reference type:   Journal article
Squib:   1993LIM/MIC3919-3928

Reaction:   CH3Cl·CH3 + ·Cl
Reaction order:   1
Temperature:   1660 - 2060 K
Pressure:  0.80 bar
Rate expression:   1.21x1010 [s-1] e-231142 [J/mole]/RT
Uncertainty:   1.28999996
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1660 6.45E2
1675 7.50E2
1700 9.57E2
1725 1.21E3
1750 1.53E3
1775 1.91E3
1800 2.37E3
1825 2.93E3
1850 3.60E3
1875 4.40E3
1900 5.35E3
1925 6.47E3
1950 7.79E3
1975 9.33E3
2000 1.11E4
2025 1.32E4
2050 1.56E4
2060 1.67E4