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Accessibility information
Author(s):   Marston, G.; Monks, P.S.; Canosa-Mas, C.E.; Wayne, R.P.
Title:   Correlations between rate parameters and calculated molecular properties in the reactions of the nitrate radical with alkenes
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   89
Page(s):   3899 - 3905
Year:   1993
Reference type:   Journal article
Squib:   1993MAR/MON3899-3905

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1993MAR/MON3899-3905   C2H4 + NO3 → Products  270 - 330   4.80E-12       2.39E04   3.15E-16  2
  1993MAR/MON3899-3905   CH2=CCl2 + NO3 → Products  270 - 330   3.90E-13       1.40E04   1.39E-15  2
  1993MAR/MON3899-3905   C2HCl3 + NO3 → Products  270 - 330   1.40E-13       1.75E04   1.22E-16  2
  1993MAR/MON3899-3905   1-C4H8 + NO3 → Products  270 - 330   1.40E-12       1.21E04   1.04E-14  2
  1993MAR/MON3899-3905   1-C5H10 + NO3 → Products  270 - 330   9.00E-13       8098   3.43E-14  2
  1993MAR/MON3899-3905   CH3CH=CH2 + NO3 → Products  270 - 330   1.10E-12       9977   1.96E-14  2
  1993MAR/MON3899-3905   iso-C4H8 + NO3 → Products  270 - 330   4.00E-13       649   3.08E-13  2
  1993MAR/MON3899-3905   C2Cl4 + NO3 → Products  270 - 330   9.00E-14       1.54E04   1.81E-16  2
  1993MAR/MON3899-3905   (Z)-CHCl=CHCl + NO3 → Products  270 - 330   1.91E-13       1.89E04   9.39E-17  2
  1993MAR/MON3899-3905   (E)-CHCl=CHCl + NO3 → Products  270 - 330   2.01E-13       1.94E04   8.08E-17  2
  1993MAR/MON3899-3905   (CH3)2C=CHCH3 + NO3 → Products  270 - 330   1.40E-13       -9229   5.80E-12  2
  1993MAR/MON3899-3905   CH3CHClCH=CH2 + NO3 → Products  270 - 330   2.19E-12       1.67E04   2.58E-15  2
  1993MAR/MON3899-3905   (CH3)2C=C(CH3)2 + NO3 → Products  270 - 330   6.91E-14       -1.59E04   4.20E-11  2
  1993MAR/MON3899-3905   2-Butene, 1-chloro- + NO3 → Products  270 - 330   8.50E-13       7599   3.96E-14  2
  1993MAR/MON3899-3905   1-C6H12 + NO3 → Products  270 - 330   9.00E-13       8098   3.43E-14  2
  1993MAR/MON3899-3905   ClCH2CH2CH=CH2 + NO3 → Products  270 - 330   1.30E-12       1.19E04   1.07E-14  2
  1993MAR/MON3899-3905   1-Butene, 2-chloro- + NO3 → Products  270 - 330   3.50E-13       1.20E04   2.79E-15  2
  1993MAR/MON3899-3905   2-Butene, 2-chloro- + NO3 → Products  270 - 330   1.50E-13       324   1.32E-13  2
  1993MAR/MON3899-3905   1-Butene, 1-chloro- + NO3 → Products  270 - 330   2.51E-13       8813   7.15E-15  2
  1993MAR/MON3899-3905   1-Butene, 4-bromo- + NO3 → Products  270 - 330   3.30E-12       2.04E04   8.88E-16  2
  1993MAR/MON3899-3905   NO3 + CH3CBr=CHCH3 (Unspecified) → Products  270 - 330   5.40E-13       3293   1.43E-13  2
  1993MAR/MON3899-3905   NO3 + 1-Butene, 3-bromo- → Products  270 - 330   2.71E-12       1.86E04   1.47E-15  2
  1993MAR/MON3899-3905   NO3 + CH3CH=CHBr → Products  270 - 330   1.10E-12       9728   2.17E-14  2

Search returned 23 records.