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Accessibility information
Author(s):   Miyoshi, A.; Ohmori, K.; Tsuchiya, K.; Matsui, H.
Title:   Reaction rates of atomic oxygen with straight chain alkanes and fluoromethanes at high temperaures
Journal:   Chem. Phys. Lett.
Volume:   204
Page(s):   241 - 247
Year:   1993
Reference type:   Journal article
Squib:   1993MIY/OHM241-247

Reaction:   n-C5H12 + → Other Products + ·OH
Reaction order:   2
Temperature:   250 - 1140 K
Pressure:  4.00E-2 - 6.67E-2 bar
Rate expression:   6.53x10-12 [cm3/molecule s] (T/298 K)(2.37±0.52) e-11391 [±2162 J/mole]/RT
Uncertainty:   1.32000005
Bath gas:   He
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
250 1.79E-14
300 6.89E-14
350 1.91E-13
400 4.27E-13
450 8.25E-13
500 1.44E-12
550 2.31E-12
600 3.49E-12
650 5.03E-12
700 6.98E-12
750 9.36E-12
800 1.22E-11
850 1.56E-11
900 1.96E-11
950 2.41E-11
1000 2.92E-11
1050 3.50E-11
1100 4.15E-11
1140 4.72E-11