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Accessibility information
Author(s):   Schmoltner, A.M.; Talukdar, R.K.; Warren, R.F.; Mellouki, A.; Goldfarb, L.; Gierczak, T.; McKeen, S.A.; Ravishankara, A.R.
Title:   Rate coefficients for reactions of several hydrofluorocarbons with OH and O(1D) and their atmospheric lifetimes
Journal:   J. Phys. Chem.
Volume:   97
Page(s):   8976 - 8982
Year:   1993
Reference type:   Journal article
Squib:   1993SCH/TAL8976-8982

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1993SCH/TAL8976-8982   O(1D) + CH2F2 → Products  298   5.13E-11           5.13E-11  2
  1993SCH/TAL8976-8982   O(1D) + CH2F2CH2F2 +   298   3.59E-11           3.59E-11  2
  1993SCH/TAL8976-8982   O(1D) + CH2F2CH2F2 +   298   0.70           0.70  2
  Reference reaction:  O(1D) + CH2F2 → Products 2
  1993SCH/TAL8976-8982   O(1D) + CHF3 → Products  298   9.75E-12           9.75E-12  2
  1993SCH/TAL8976-8982   O(1D) + CHF3CHF3 +   298   9.96E-12           9.96E-12  2
  1993SCH/TAL8976-8982   O(1D) + CHF3CHF3 +   298   1.02           1.02  2
  Reference reaction:  O(1D) + CHF3 → Products 2
  1993SCH/TAL8976-8982   O(1D) + C2H5F → Products  298   2.61E-10           2.61E-10  2
  1993SCH/TAL8976-8982   O(1D) + C2H5FC2H5F +   298   4.70E-11           4.70E-11  2
  1993SCH/TAL8976-8982   O(1D) + C2H5FC2H5F +   298   0.18           0.18  2
  Reference reaction:  O(1D) + C2H5F → Products 2
  1993SCH/TAL8976-8982   O(1D) + CHF2CF2CF2CHF2 → Products  298   1.76E-11           1.76E-11  2
  1993SCH/TAL8976-8982   O(1D) + CHF2CF2CF2CHF2CHF2CF2CF2CHF2 +   298   1.71E-11           1.71E-11  2
  1993SCH/TAL8976-8982   O(1D) + CHF2CF2CF2CHF2CHF2CF2CF2CHF2 +   298   0.97           0.97  2
  Reference reaction:  O(1D) + CHF2CF2CF2CHF2 → Products 2
  1993SCH/TAL8976-8982   O(1D) + CH3F → Products  298   1.65E-10           1.65E-10  2
  1993SCH/TAL8976-8982   O(1D) + CH3FCH3F +   298   1.83E-11           1.83E-11  2
  1993SCH/TAL8976-8982   O(1D) + CH3FCH3F +   298   0.11           0.11  2
  Reference reaction:  O(1D) + CH3F → Products 2
  1993SCH/TAL8976-8982   O(1D) + CF3CHFCHFCF2CF3 → Products  298   2.06E-10           2.06E-10  2
  1993SCH/TAL8976-8982   O(1D) + CF3CHFCHFCF2CF3 + CF3CHFCHFCF2CF3  298   1.88E-10           1.88E-10  2
  1993SCH/TAL8976-8982   O(1D) + CF3CHFCHFCF2CF3 + CF3CHFCHFCF2CF3  298   0.91           0.91  2
  Reference reaction:  OD + CF3CHFCHFCF2CF3 → Products 2
  1993SCH/TAL8976-8982   CHF3 + ·OH·CF3 + H2O  252 - 374   6.94E-13       1.91E04   3.09E-16  2
  1993SCH/TAL8976-8982   C2H5F + ·OH → Other Products + H2O  243 - 373   2.69E-12       6236   2.17E-13  2
  1993SCH/TAL8976-8982   CHF2CF2CF2CHF2 + ·OH → CHF2CF2CF2CF2· + H2O  232 - 378   7.72E-13       1.29E04   4.25E-15  2
  1993SCH/TAL8976-8982   CH3F + ·OH·CH2F + H2O  243 - 373   1.74E-12       1.08E04   2.22E-14  2
  1993SCH/TAL8976-8982   ·OH + CF3CHFCHFCF2CF3 → Other Products + H2O  251 - 375   6.46E-13       1.33E04   3.01E-15  2

Search returned 23 records.