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Accessibility information
Author(s):   Semadeni, M.; Stocker, D.W.; Kerr, J.A.
Title:   Further studies of the temperature dependence of the rate coefficients for the reactions of OH with a series of ethers under simulated atmospheric conditions
Journal:   J. Atmos. Chem.
Volume:   16
Page(s):   79 - 93
Year:   1993
Reference type:   Journal article
Squib:   1993SEM/STO79-93

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1993SEM/STO79-93   (C2H5)2O + ·OH → Other Products + H2O  250 - 373   5.20E-12       -2178   1.25E-11  2
  1993SEM/STO79-93   (C2H5)2O + ·OH → Other Products + H2O  250 - 373   0.83       -2178   2.00  2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·OH → Other Products + H2O 2
  1993SEM/STO79-93   (n-C4H9)2O + ·OH → Other Products + H2O  247 - 373   0.69       -2993   2.31  2
  Reference reaction:  (C2H5)2O + ·OH → Other Products + H2O 2
  1993SEM/STO79-93   (n-C4H9)2O + ·OH → Other Products + H2O  247 - 373   0.91       -2478   2.47  2
  Reference reaction:  (C2H5)2O + ·OH → Other Products + H2O 2
  1993SEM/STO79-93   (n-C4H9)2O + ·OH → Other Products + H2O  250 - 353   5.50E-12       -4174   2.96E-11  2
  1993SEM/STO79-93   (n-C4H9)2O + ·OH → Other Products + H2O  250 - 353   1.01       -3974   5.02  2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·OH → Other Products + H2O 2
  1993SEM/STO79-93   CH3CH2CH2CH2OCH3 + ·OH → Other Products + H2O  247 - 353   5.40E-12       -2569   1.52E-11  2
  1993SEM/STO79-93   CH3CH2CH2CH2OCH3 + ·OH → Other Products + H2O  247 - 373   0.87       -2569   2.46  2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·OH → Other Products + H2O 2
  1993SEM/STO79-93   n-C4H9OC2H5 + ·OH → Other Products + H2O  248 - 353   7.31E-12       -2785   2.25E-11  2
  1993SEM/STO79-93   n-C4H9OC2H5 + ·OH → Other Products + H2O  248 - 373   1.18       -2785   3.63  2
  Reference reaction:  (CH3)2CHCH(CH3)2 + ·OH → Other Products + H2O 2
  1993SEM/STO79-93   (n-C5H11)2O + ·OH → Other Products + H2O  263 - 373   8.50E-12       -3467   3.45E-11  2
  1993SEM/STO79-93   (n-C5H11)2O + ·OH → Other Products + H2O  263 - 373   1.66       840   1.18  2
  Reference reaction:  (n-C4H9)2O + ·OH → Other Products + H2O 2

Search returned 12 records.