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Author(s):   Semadeni, M.; Stocker, D.W.; Kerr, J.A.
Title:   Further studies of the temperature dependence of the rate coefficients for the reactions of OH with a series of ethers under simulated atmospheric conditions
Journal:   J. Atmos. Chem.
Volume:   16
Page(s):   79 - 93
Year:   1993
Reference type:   Journal article
Squib:   1993SEM/STO79-93

Reaction:   (n-C5H11)2O + ·OH → Other Products + H2O
Reaction order:   2
Reference reaction:   (n-C4H9)2O + ·OH → Other Products + H2O
Temperature:   263 - 373 K
Pressure:  1.01 bar
Rate expression:   8.5x10-12 [cm3/molecule s] e3467 [±1247 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
263 4.15E-11
275 3.87E-11
300 3.41E-11
325 3.07E-11
350 2.80E-11
373 2.60E-11