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Accessibility information
Author(s):   Wallington, T.J.; Hurley, M.D.; Shi, J.; Maricq, M.M.; Sehested, J.; Nielsen, O.J.; Ellermann, T.
Title:   A kinetic study of the reaction of fluorine atoms with CH3F, CH3Cl, CH3Br, CF2H2, CO, CF3H, CF3CHCl2, CF3CH2F, CHF2CHF2, CF2ClCH3, CHF2CH3, and CF3CF2H at 295 ± 2 K
Journal:   Int. J. Chem. Kinet.
Volume:   25
Page(s):   651 - 665
Year:   1993
Reference type:   Journal article
Squib:   1993WAL/HUR651-665

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1993WAL/HUR651-665   CH3Br + ·F → Products  295   3.01E-11              2
  1993WAL/HUR651-665   CH3Br + ·F → Products  295   0.44              2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1993WAL/HUR651-665   CH3Cl + ·F → Products  295   3.30E-11              2
  1993WAL/HUR651-665   CH3Cl + ·F → Products  295   0.48              2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1993WAL/HUR651-665   CH2F2 + ·F·CHF2 + HF  295   4.30E-12              2
  1993WAL/HUR651-665   CH2F2 + ·F·CHF2 + HF  295   0.06              2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1993WAL/HUR651-665   CH3CHF2 + ·F → Other Products + HF  295   1.69E-11              2
  1993WAL/HUR651-665   CH3CHF2 + ·F → Other Products + HF  295   0.25              2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1993WAL/HUR651-665   CHF3 + ·F·CF3 + HF  295   1.40E-13              2
  1993WAL/HUR651-665   CHF3 + ·F·CF3 + HF  295   2.00E-03              2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1993WAL/HUR651-665   CH3CF2Cl + ·F → Products  295   3.90E-12              2
  1993WAL/HUR651-665   CH3CF2Cl + ·F → Products  295   0.06              2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1993WAL/HUR651-665   CF3CHCl2 + ·FHF + CF3CCl2  295   1.20E-12              2
  1993WAL/HUR651-665   C2F5H + ·FC2F5 + HF  295   3.50E-13              2
  1993WAL/HUR651-665   C2F5H + ·FC2F5 + HF  295   5.20E-03              2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1993WAL/HUR651-665   CHF2CHF2 + ·FHF + CHF2CF2  295   1.00E-12              2
  1993WAL/HUR651-665   CHF2CHF2 + ·FHF + CHF2CF2  295   0.01              2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1993WAL/HUR651-665   CH3F + ·F → Products  295   3.70E-11              2
  1993WAL/HUR651-665   CH3F + ·F → Products  295   0.54              2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1993WAL/HUR651-665   CO + ·FFCO  295   5.50E-13              2
  1993WAL/HUR651-665   CF3CH2F + ·FHF + CF3CHF  295   1.30E-12              2
  1993WAL/HUR651-665   CF3CH2F + ·FHF + CF3CHF  295   0.02              2
  Reference reaction:  CH4 + ·F·CH3 + HF 2

Search returned 22 records.