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Accessibility information
Author(s):   Williams, D.C.; O'rji, L.N.; Stone, D.A.
Title:   Kinetics of the reactions of OH radicals with selected acetates and other esters under simulated atmospheric conditions
Journal:   Int. J. Chem. Kinet.
Volume:   25
Page(s):   539 - 548
Year:   1993
Reference type:   Journal article
Squib:   1993WIL/ORJ539-548

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1993WIL/ORJ539-548   CH3COOCH2CH2CH3 + ·OH → Other Products + H2O  297   3.42E-12              2
  1993WIL/ORJ539-548   CH3COOCH2CH2CH3 + ·OH → Other Products + H2O  297   0.13              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1993WIL/ORJ539-548   2-Ethoxyethyl acetate + ·OH → Products  297   1.05E-11              2
  1993WIL/ORJ539-548   2-Ethoxyethyl acetate + ·OH → Products  297   0.40              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1993WIL/ORJ539-548   CH3COO(CH2)3CH3 + ·OH → Other Products + H2O  297   5.71E-12              2
  1993WIL/ORJ539-548   CH3COO(CH2)3CH3 + ·OH → Other Products + H2O  297   0.22              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1993WIL/ORJ539-548   Acetic acid, pentyl ester + ·OH → Products  297   7.51E-12              2
  1993WIL/ORJ539-548   Acetic acid, pentyl ester + ·OH → Products  297   0.29              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1993WIL/ORJ539-548   Ethyl 3-ethoxyacrylate + ·OH → Products  297   3.32E-11              2
  1993WIL/ORJ539-548   Ethyl 3-ethoxyacrylate + ·OH → Products  297   0.52              2
  Reference reaction:  (E)-2-C4H8 + ·OH → Products 2
  1993WIL/ORJ539-548   CH3C(O)O(CH2)3CH=CH2 + ·OH → Products  297   4.33E-11              2
  1993WIL/ORJ539-548   CH3C(O)O(CH2)3CH=CH2 + ·OH → Products  297   1.65              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1993WIL/ORJ539-548   2-Ethoxyethyl methacrylate + ·OH → Products  297   2.72E-11              2
  1993WIL/ORJ539-548   2-Ethoxyethyl methacrylate + ·OH → Products  297   1.04              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1993WIL/ORJ539-548   ·OH + 2-Ethoxyethyl isobutyrate → Products  297   1.36E-11              2
  1993WIL/ORJ539-548   ·OH + 2-Ethoxyethyl isobutyrate → Products  297   0.51              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2

Search returned 16 records.