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Accessibility information
Author(s):   Zhdanov, G.F.
Title:   The kinetic regularities of cooperative action of two halogens in the radical substitution of hydrogen: II. Acceleration of gas-phase chlorination of CF3H
Journal:   Kinet. Catal.
Volume:   34
Page(s):   871 - 877
Year:   1993
Reference type:   Journal article
Squib:   1993ZHD871-877

Reaction:   CHF3 + Cl2CF3Cl + HCl
Reaction order:   2
Temperature:   603 - 693 K
Rate expression:   8.3x10-12 [cm3/molecule s] e-142177 [±5687 J/mole]/RT
Uncertainty:   2.0
Bath gas:   CHF3
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
603 4.01E-24
625 1.09E-23
650 3.12E-23
675 8.26E-23
693 1.60E-22