NIST Chemical Kinetics Database

Author(s):   Baulch, D.L.; Cobos, C.J.; Cox, R.A.; Frank, P.; Hayman, G.; Just, Th.; Kerr, J.A.; Murrells, T.; Pilling, M.J.; Troe, J.; Walker, R.W.; Warnatz, J.
Title:   Evaluated kinetic data for combusion modelling. Supplement I
Journal:   J. Phys. Chem. Ref. Data
Volume:   23
Page(s):   847 - 1033
Year:   1994
Reference type:   Journal article
Squib:   1994BAU/COB847-1033

Reaction:   Toluene → Benzyl + H·
Reaction order:   1
Temperature:   920 - 2200 K
Rate expression:   3.1x10¹⁵ [s^-1] e^{-373320 [J/mole]/RT}
Uncertainty:   3.16000009
Category: Review
Data type:   Extensive literature review

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [s^-1]
920	1.98E-6
1000	9.81E-5
1100	5.81E-3
1200	1.74E-1
1300	3.10E0
1400	3.66E1
1500	3.10E2
1600	2.01E3
1700	1.05E4
1800	4.55E4
1900	1.69E5
2000	5.51E5
2100	1.61E6
2200	4.24E6