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Accessibility information
Author(s):   Hippler, H.; Seisel, S.; Troe, J.
Title:   Pyrolysis of p-xylene and of 4-methylbenzyl radicals
Journal:   Symp. Int. Combust. Proc.
Volume:   25
Page(s):   875 - 882
Year:   1994
Reference type:   Journal article
Squib:   1994HIP/SEI875-882

Reaction:   1,4-Dimethylbenzene4-Methylbenzyl +
Reaction order:   1
Temperature:   1000 - 1800 K
Pressure:  2.40E-2 - 0.25 bar
Rate expression:   5.01x1015 [s-1] e-355028 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 1.43E-3
1050 1.09E-2
1100 6.94E-2
1150 3.75E-1
1200 1.76E0
1250 7.32E0
1300 2.72E1
1350 9.19E1
1400 2.84E2
1450 8.14E2
1500 2.17E3
1550 5.44E3
1600 1.29E4
1650 2.89E4
1700 6.19E4
1750 1.27E5
1800 2.50E5