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Accessibility information
Author(s):   Hsu, K.-J.; DeMore, W.B.
Title:   Rate constants for the reactions of OH with CH3Cl, CH2Cl2, CHCl3, and CH3Br
Journal:   Geophys. Res. Lett.
Volume:   21
Page(s):   805 - 808
Year:   1994
Reference type:   Journal article
Squib:   1994HSU/DEM805-808

Reaction:   CH2Cl2 + ·OHCHCl2 + H2O
Reaction order:   2
Reference reaction:   CH3CHF2 + ·OH → Other Products + H2O
Reference reaction order:   2
Temperature:   293 - 360 K
Pressure:  1.01 bar
Rate expression:   9.71x10-1±8.7x10-2 e2444 [±244 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
293 2.65E0
300 2.59E0
325 2.40E0
350 2.25E0
360 2.20E0