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Accessibility information
Author(s):   Humpfer, R.; Oser, H.; Grotheer, H-H.; Just, T.
Title:   The reaction system CH3 + OH at intermediate temperatures. Appearance of a new product channel
Journal:   Symp. Int. Combust. Proc.
Volume:   25
Page(s):   721 - 731
Year:   1994
Reference type:   Journal article
Squib:   1994HUM/OSE721-731

Reaction:   ·CH3 + ·OHCH3OH
Reaction order:   3
Temperature:   300 - 700 K
Pressure:  6.53E-4 - 3.25E-3 bar
Rate expression:   3.69x10-29 [cm6/molecule2 s] e10643 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
300 2.63E-27
325 1.90E-27
350 1.43E-27
375 1.12E-27
400 9.06E-28
425 7.51E-28
450 6.35E-28
475 5.47E-28
500 4.78E-28
525 4.23E-28
550 3.79E-28
575 3.42E-28
600 3.12E-28
625 2.86E-28
650 2.65E-28
675 2.46E-28
700 2.30E-28