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Author(s):   Jefferson, A.; Nicovich, J.M.; Wine, P.H.
Title:   Temperature-dependent kinetics studies of the reactions Br(2P3/2) + CH3SCH3 = CH3SCH2 + HBr. Heat of formation of the CH3SCH2 radical
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   7128 - 7135
Year:   1994
Reference type:   Journal article
Squib:   1994JEF/NIC7128-7135

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1994JEF/NIC7128-7135   (CH3)2S + Br·HBr + CH3SCH2  386 - 604   9.00E-11       1.99E04      2
  1994JEF/NIC7128-7135   HBr + CH3SCH2(CH3)2S + Br·  386 - 604   8.60E-13       -6951      2

Search returned 2 records.