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Author(s):   Kukui, A.S.; Jungkamp, T.P.W.; Schindler, R.N.
Title:   Determination of the rate constant and of product branching ratios in the reaction of CH3O2 with OCl between 233 and 300 K
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   98
Page(s):   1298 - 1302
Year:   1994
Reference type:   Journal article
Squib:   1994KUK/JUN1298-1302

Reaction:   CH3O2· + ClOCH3 + ClOO
Reaction order:   2
Temperature:   233 - 300 K
Pressure:  5.00E-3 - 6.00E-3 bar
Rate expression:   5.0x10-12 [±9.96x10-13 cm3/molecule s] e-416 [±665 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
233 4.03E-12
250 4.09E-12
275 4.17E-12
300 4.23E-12