Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Lim, K.P.; Michael, J.V.
Title:   Thermal decomposition of COCl2
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   211 - 215
Year:   1994
Reference type:   Journal article
Squib:   1994LIM/MIC211-215

Reaction:   COCl2CO + Cl2
Reaction order:   1
Temperature:   1400 - 2000 K
Pressure:  8.00E-3 - 2.13E-2 bar
Rate expression:   1.45x1014 [s-1] e-345051 [J/mole]/RT
Bath gas:   He
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1400 1.94E1
1450 5.39E1
1500 1.40E2
1550 3.42E2
1600 7.89E2
1650 1.73E3
1700 3.63E3
1750 7.28E3
1800 1.41E4
1850 2.62E4
1900 4.74E4
1950 8.29E4
2000 1.41E5