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Accessibility information
Author(s):   Lim, K.P.; Michael, J.V.
Title:   Thermal decomposition of COCl2
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   211 - 215
Year:   1994
Reference type:   Journal article
Squib:   1994LIM/MIC211-215

Reaction:   COCl2CO + Cl2
Reaction order:   1
Temperature:   1400 - 2000 K
Pressure:  8.00E-3 - 2.13E-2 bar
Rate expression:   1.45x1014 [s-1] e-345051 [J/mole]/RT
Bath gas:   He
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1400 1.94E1
1450 5.39E1
1500 1.40E2
1550 3.42E2
1600 7.89E2
1650 1.73E3
1700 3.63E3
1750 7.28E3
1800 1.41E4
1850 2.62E4
1900 4.74E4
1950 8.29E4
2000 1.41E5