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Accessibility information
Author(s):   Lim, K.P.; Michael, J.V.
Title:   Thermal decomposition ofCH2Cl2
Journal:   Symp. Int. Combust. Proc.
Volume:   25
Page(s):   809 - 816
Year:   1994
Reference type:   Journal article
Squib:   1994LIM/MIC809-816

Reaction:   CH2Cl2·CH2Cl + Cl
Reaction order:   1
Temperature:   1400 - 2300 K
Pressure:  8.00E-3 - 2.13E-2 bar
Rate expression:   1.33x1016 [±2.7x1014 s-1] e-324264 [J/mole]/RT
Bath gas:   Kr
Category:  Experiment
Data type:   Derived from detailed balance/reverse rate

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1400 1.06E4
1450 2.77E4
1500 6.80E4
1550 1.57E5
1600 3.45E5
1650 7.22E5
1700 1.45E6
1750 2.79E6
1800 5.18E6
1850 9.30E6
1900 1.62E7
1950 2.74E7
2000 4.52E7
2050 7.27E7
2100 1.14E8
2150 1.76E8
2200 2.66E8
2250 3.95E8
2300 5.75E8